No surprises here. The Army of Northern Virginia was hands down, the most effective CSA fighting force. I'm sure there are metrics to prove that statement given that the ANV managed to fight and win enough of its battles too hold off federal armies for many long years. If the confederacy could have prevailed in the war, it would have been because of the efforts of the ANV.
The total battle casualties taken by the AoNV during its time were on the order of 180,000 to 190,000; against most generals Lee inflicted more casualties than he took, an impressive feat for the smaller army (especially when in many cases Lee's army engaged full-bloodedly rather than fight in Fabian style). For example:
Pope (Northern Virginia campaign)
Lee inflicts about 16,800 casualties while taking about 9,200 - nearly a 2:1 exchange rate in favour of his army.
Burnside (Fredericksburg campaign)
This was mostly one battle, but it should be obvious. 12,650 casualties inflicted for 4,200 taken.
Hooker (Chancellorsville campaign)
17,300 casualties inflicted, 13,300 taken.
Meade (Gettysburg campaign)
32,000 inflicted for about 30,000 sustained.
Grant (Overland-Petersburg)
About 100,000 casualties inflicted for about 55,000 taken.
Given that in most cases military theory suggests the smaller army should take higher
absolute casualties in battle (because, well, it's outnumbered), this is a good record indeed. Ignoring McClellan, Sheridan and the Appomattox surrender (the last being because it's not really "battlefield" as such), the AoNV took about 112,000 casualties to inflict about 180,000.
That being said, it's not the same as saying the AoNV was elite...