I don't believe any legions in the ACW ever actually fought as a combined force. As mentioned, most were separated early in the war or never fought together in battle as intended. For instance, the infantry battalion of Hampton's Legion served in Hood's Texas Brigade, was later consolidated with another unit in late 1862 to form a full regiment and was mounted in 1864. IIRC, the the cavalry contingent was organized into the 2nd South Carolina Cavalry and the artillery served as a separate horse artillery battery.
As to Union legions, there was the 10th Legion, also known as the 56th New York Infantry, which contained eleven infantry companies, two light batteries, and two troops of cavalry. But, as usual, the infantry, cavalry and artillery were soon separated and organized into different units.