Yes he did.
Service record:
Boone, Thomas D.
Resided in Hertfort County where he enlisted at age 20, July 5, 1861, for the war. Mustered in as 1st Sergeant and appointed 2nd Lieutenant September 9, 1862. Promoted to 1st Lieutenant to rank from November 19, 1862, and to Captain on July 29, 1863. Admitted to hospital at Charlottesville Virginia, September 25, 1864 with a gunshot wound of the chest. Date and place he received the wound not reported present or accounted for until paroled at Appomattox Court House, Virginia, April 9, 1865. Page 201.
Addenda: Born in North Hampton County and was by occupation a teacher. Received a shell wound in the head at Chancellorsville, Virginia May 3, 1863. Wounded in the side at Winchester, Virginia, September 19, 1864. Page 669.
North Carolina Troops, 1861-1865, A Roster, Vol. III Infantry, 1st- 3rd regiments, Misc. Units
Captain Boone had two brothers in Company F.
James D. Boone until transferred to Field and Staff upon appointment to Quartermaster Sergeant November-December 1862.
Pvt. John W. Boone died of disease at Fredericksburg, Virginia, December 18, 1861.