Sorry I am late to this discussion.
Respectfully, I am very curious about the source of your statement that the Turks fired their own ships at the Battle of Sinop and that Russian explosive shells were "largely ineffective". Every source I've read about Sinop attribute the destruction of the Turkish squadron to delayed action explosive shells fired from Paixhans guns mounted aboard the Russian ships.
Yes, because that's what was reported by the French ambassador. The Russians reported the shell guns performed poorly.
The battleships expended:
- Imperatritsa Maria: Expended 176x 68 pdr (5 being shells), 1,361x 36 pdr shot and 619x 24 pdr shot (2,128 rds)
- Velikiy Knyaz Konstantin: Expended 457x 68 pdr (30 being shells), 1,529x 36 pdr shot and 480x 24 pdr shot (2,466 rds)
- Chesma: not engaged with the enemy ships, engaged coastal batteries
- Tri Sviatitelia: damaged by coastal batteries and turned away, not engaging the enemy ships
- Parizh: Expended 893x 68 pdr (70 being shells), 2,111x 36 pdr and 940x 12 pdr (3,952 rds)
- Rostislav: Expended 400x 68 pdr (16 being shells, but most used as "hollow shot"), 2,800x 36 pdr (1,000 of these were double-shotted) and 760 24 pdrs (3,960 rds)
A maximum of 121 shells were fired against the Turkish ships by the battleships, of 12,506 rds fired (ca. 1%). However, the Russians used three natures of shell, in addition to solid shot and grape from the 68 pdr:
- Unfilled shell used as "hollow shot"
- Powder filled explosive shells
- Incendiary filled "brandskugels" filled with pitch etc.
Most of the shells used seem to be hollow shot. Explosive shells were avoided, and only 5 rpg were carried. They were carried in a bomb-cellar deep on the ship, and required to be fuzed down there and brought up individually when needed.
The Russians, through maneouvering, got themselves into a position where they could shoot down the Ottoman line with little return fire, and proceeded to smash the enemy with a massive weight of conventional shot. The explosive shell was largely a non-factor, and the Russians noted how
ineffective the shells had been.
It's been about 15 years since I looked into this, but my memory is that the Ottoman accounts have them beaching their overwhelmed ships and trying to fire them (not always successfully). One of those that exploded was, ISTR, an officer going below and deliberately lighting the powder magazine after the ship was abandoned.
You will note that in future conflicts, like the ACW, shells showed no incendiary effect.