I'll also point out that it's the British Army, not the Royal Army. Regiments and components therein are Royal, but the whole is not.
The British Army is composed almost entirely of men who would be considered expert shots by US standards - and by that I mean "qualified for the US Sharpshooters" because the Sharpshooters went through much the same musketry training that was given to every British recruit. Even the cavalry and the gunners were taught to sharpshoot with their short Enfields, and it had become so much an obsession that around this time there are questions raised in Parliament as to whether the Irish Constabulary really need to be trained as battle sharpshooters...
British troops are long-service at this time, and a typical infantry battalion will probably have about 6-7 years' experience as the average per-man (with the most grizzled veterans having been in for up to 22 years - they enlisted for ten and could choose to enlist for another twelve, an option which 50% of those discharged took immediately and another 10% did within six months.) The effect of this on the quality of the drill is significant, and it also means that the fraction of men in any given battalion who have not been through multiple runs of the yearly musketry qualification course will be very low.
Importantly, the equipment is pretty standardized in most cases and there are full support arms. Some cavalry regiments were trialling breechloaders, but apart from that:
All artillery is Armstrong breech loading rifles, and the gunners have Enfields as personal weapons. Batteries are "fully manned" and have been for years, which means that rather than the prewar US situation where there were only a couple of dozen trained gun captains each battery comes with a full set of trained personnel (and is at 250 men per battery, so there's no need to draft in men from the infantry to help provide gun labour).
All infantry have the Enfield, rather than the kind of slightly chaotic mess that prevailed even as late as Gettysburg.
All cavalry is in practice trained to act as both shock troops and dragoons, plus being capable of the usual scouting and screening.
The logistics and engineering is handled by separate organizations (the Military Train and Royal Engineers) and so there's none of the usual concern with troops detached to the logistics.
I'll now digress to the Armstrong, because it has a bad reputation it does not deserve.
We should first point out that the reason the Armstrong was rejected was ultimately its tendency for breech blowouts in the larger calibres (the vent piece would blow - each gun carried two spares, it was a bit of safety equipment), but nobody seems to have ever died from an Armstrong gun having a vent piece burst; compare with the larger Parrotts, which were a bit more lethal.
The Armstrong, especially in field gun calibres, is a reliable, accurate, versatile and powerful artillery piece. Tests showed this as such:
Reliable -
"As regards the care of the gun I find no difficulty in keeping it in perfect order in all weathers and all circumstances" (Major Govan, RA)
"On one occasion his guns had very rough work indeed. They were sent out with a division of the army over a swamp, the very worst ground possible for artillery. The guns were in fact almost swallowed up, and were covered with mud when brought into action, but no impediment occurred." (Major Govan, RA)
"On two occasions vent-pieces were blown away; on the last occasion I happened to come up to the gun almost immediately after it had occurred... The traversing screw was jammed, but the gun was not otherwise injured, and with another vent-piece was again serviceable." (Major Hay, RA)
"As a preliminary measure, a new 12-pounder gun, No. 8, was left exposed to the weather without any protection, and untouched, ... [for] 45 days. It rained very constantly during this period... At the expiration of it, it was taken to the marshes, and fired without being cleaned or sponged." (Report from the Select Committee on Ordnance, 23 July 1863)
Accurate -
"The last gun made by Sir W. Armstrong and sent to be tried, was a 12-pounder. The following was the result:—Forty consecutive rounds were fired from the new 12-pounder field gun of 8 cwt., with theminimum charge of 11 lb. 8oz. of slow powder. Experiment shows that we have been wrong for some time in using powder of so quick a detonating nature for artillery practice, and especially for rifled cannon, which require slower powder than that suited to other arms. At seven degrees of elevation in five rounds, the range being from 2,465 to 2,495 yards, the difference in the range was 65 yards, and the greatest difference in width three yards. Then at eight degrees of elevation, the range reaching 2,797 yards, with 60 yards of difference between the five shots, and only one yard of difference in the width. Again, at nine degrees of elevation the range comes up to 3,000 yards and upwards, with 85 yards difference between the five shots, and three yards as the greatest difference in the width. In point of fact, almost all of these shots but three or four would have struck within a 9-feet target. The rapidity and accuracy with which small objects are hit at a great distance in the practice made at Shoeburyness, is something marvellous. "
(HC debates, Feb 1860)
"The 40-pounder we found answer exceedingly well, for coming out of the place we planted common shell, with pillar fuze, wherever we wished, at a range of 3,800 yards. "
- shipboard use on the Euryalus, as per the gunnery lieutenant on board that ship.
Versatile -
The Armstrong gun carries a standardized but expensive "segment" shell that can be fired in four different modes. It can be used with a time fuze as a shrapnel round, with a Pillar percussion fuze as a contact explosive, with a plug in the shell hole as a shot or bolt, and with nothing in the fuze hole as cannister (as it bursts instantly).
This is important as it means a battery can't be caught with the wrong type of ammunition. The fuzes are also reliable (which is a point of merit over American fuzes, which had something of a failure rate).
The Segment shell was less effective in any given role than what it replaced, but the versatility was useful (though the tradeoff was hotly debated).
Powerful -
In testing, the 12 pounder firing segment shell penetrated 4 feet of artificial earthwork or 3 feet 2 in of gravel clay in natural buttress. This proved to be capable of firing at a rifle pit, penetrating it and (with percussion shell) bursting inside. Mercer of the Royal Artillery, on his time in New Zealand:
'The guns were loaded and laid, and the gunners with lanyard in hand waited for the word from the officer, who was watching until some heads appeared above in that direction, or a puff of smoke revealed their presence, when the gun was instantly fired, and the shell, entering just below the crest of their pits, burst inside.
'The following evidence has been given concerning the action of the Armstrong shell with the concussion fuze (i.e., percussion fuze) only:- Colour-Serjeant J. Morant, Royal Engineers, was at the head of the sap, and saw an Armstrong shell go through a rifle pit, about four feet of earth, and burst inside, and heard the enemy shout as in pain; he also observed that the shell from the Armstrong gun entered the rifle pits as soon or sooner than the report was heard, so that the natives had not time to get out of the way. Bomber J. Singer, No. 3 Battery, 12th Brigade RA, was at the head of the sap, and in the advance parallel with the Coehorn mortars, when he saw several shell from the Armstrong gun go through the enemy's rifle pits and burst inside. After the cessation of hostilities one of the natives told my sergeant-major that they were sometimes able to get out of the way of the mortar or large shells, but never out of the way of the shell (whether with time or concussion, or concussion fuze only) from the gun "all the same as the rifle," meaning the Armstrong guns, as the shell was amongst them as soon as they heard the report. These natives have designated the Armstrong shell "the quick shell".
'The different statements made both by those who were in the sap as well as by the natives themselves corroborate the observations taken from the battery, viz., that the Armstrong shell only entered the crest of the enemy's rifle pits and burst inside; whether there were few or many natives in the pit at the time cannot be ascertained.'
When the Armstrong started to use common shell instead of segment shell (in 1865) for the purpose of shelling, the bursting charge was 269 grams - which is compared to 167 grams for the 3" rifle. Obviously in 1863 they're using the segment shell instead, but it demonstrates that the Armstrong was not weaker than the 3" rifle for shelling purposes.