Simon Bolivar Butler was Inspector General and Commander of the Kentucky State Guard.
By July 1861, two State Guard Regiments was reorganized for Confederate service at Camp Boone. Roger Hansons State Guard Regiment became the 2nd Kentucky and another state Guard Regiment became to 3rd Kentucky.
It's hard to find any organization charts, but there is some info in the link above. Looks like companies was scattered around in various cities and towns.
Anyway, here are the staff of the state guard 1860-61:
Major General S. B. Buckner, Inspector General, and Commander of Kentucky State Guard
Colonel Frank Tryon, Assistant Quartermaster General, Assistant Commissary-General
Colonel Benjamin Hardin Helm, Assistant Inspector-General, Assistant Adjutant-General
Colonial Isaac W. Scott, Assistant Surgeon-General
Colonel Charles D. Pennebaker, Assistant Paymaster General
Colonel Samuel Gill, Chief Engineer
Major James A. Beattie , Judge-Advocate
Captain Philip Vacaro, Captain in the Subsistence Department
Rev. James Craik, Chaplain
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